FREE BOOKS

Author's List




PREV.   NEXT  
|<   221   222   223   224   225   226   227   228   229   230   231   232   233   234   235   236   237   238   239   240   241   242   243   244   245  
246   247   248   249   250   251   252   253   254   255   256   257   258   259   260   261   262   263   264   265   266   267   268   269   270   >>   >|  
composition and treatment of the electrolyte is thus apparent. The advantage of keeping the solution in motion is due partly to the renewal of solution thus effected in the neighbourhood of the electrodes, and partly to the neutralization of the tendency of liquids undergoing electrolysis to separate into layers, due to the different specific gravities of the solutions flowing from the opposing electrodes. Such an irregular distribution of the bath, with strong copper sulphate solution from the anode at the bottom and acid solution from the cathode at the top, not only alters the conductivity in different strata and so causes irregular current-distribution, but may lead to the current-density in the upper layers being too great for the proportion of copper there present. Irregular and defective deposits are therefore obtained. Provision for circulation of solution is made in the systems of copper-refining now in use. Henry Wilde, in 1875, in depositing copper on iron printing-rollers, recognized this principle and rotated the rollers during electrolysis, thereby renewing the surfaces of metal and liquid in mutual contact, and imparting sufficient motion to the solution to prevent stratification; as an alternative he imparted motion to the electrolyte by means of propeller blades. Other workers have followed more or less on the same lines; reference may be made to the patents of F. E. and A. S. Elmore, who sought to improve the character of the deposit by burnishing during electrolysis, of E. Dumoulin, and Sherard Cowper-Coles (_Engineering Review_, 1905, vol. xiii. p. 392), who prefers to rotate the cathode at a speed that maintains a peripheral velocity of at least 1000 ft. per minute. Certain other inventors have applied the same principle in a different way. H. Thofehrn in America and J. C. Graham in England have patented processes by which jets of the electrolyte are caused to impinge with considerable force upon the surface of the cathode, so that the renewal of the liquid at this point takes place very rapidly, and current-densities per sq. ft. of 50 to 100 amperes are recommended by the former, and of 300 amperes by the latter. Graham has described experiments in this direction, using a jet of electrolyte forced (beneath the surface of the bath) through a hole in the anode upon the surface of the cathode. Whilst the jet was playing, a good dep
PREV.   NEXT  
|<   221   222   223   224   225   226   227   228   229   230   231   232   233   234   235   236   237   238   239   240   241   242   243   244   245  
246   247   248   249   250   251   252   253   254   255   256   257   258   259   260   261   262   263   264   265   266   267   268   269   270   >>   >|  



Top keywords:

solution

 

cathode

 
electrolyte
 

copper

 
current
 

surface

 

electrolysis

 

motion

 

liquid

 

principle


Graham

 
rollers
 

distribution

 

irregular

 
renewal
 
partly
 
layers
 

amperes

 

electrodes

 
Elmore

maintains
 

velocity

 

minute

 

peripheral

 
sought
 
rotate
 

Dumoulin

 

Sherard

 

Cowper

 

Engineering


Review
 

character

 

improve

 

Certain

 

deposit

 

burnishing

 

prefers

 

considerable

 

experiments

 
recommended

direction

 
playing
 
Whilst
 

forced

 

beneath

 
densities
 

rapidly

 
England
 

patented

 
America